Second, John Rolfe fell in love with Princess Pocahontas. He asked for and received permission from the Governor of Virginia to marry Pocahontas, recognizing that interracial marriage was at least discouraged if not prohibited. No white man had ever married a Native American. He also asked for and received permission from Pocahontas’ father, Chief Powhatan, the paramount chief of 31 Algonquin tribes. John Rolfe and Princess Pocahontas were married on April 5, 1614.